You can easily upgrade to newest CentOS version if you are use a dedicated server or Xen VPS,KVM VPS,HVM VPS. But you can not upgrade if your VPS is based on OpenVz
How upgrade CentOS 6.3 to 6.4/6.5/6.6 or from CentOS 5.x to 5.9?
Make sure your server is a dedicated server or Xen VPS,KVM VPS,HVM VPS
Backup data
SSH login via root and run command "yum -y upgrade"
Wait 10-60 minutes, done!
Check CentOS version by command "cat /etc/redhat-release"
NOTE:
You can not upgrade from CentOS 5.x to 6.x
We recommand you upgrade ASAP after reload OS if you want try new version...